A Strategy for Thermal Hazards Assessment in Batch Chemical Manufacturing

A strategy has been developed for the assessment of both thermal decomposition hazards and thermal runaway potential in intended exothermic reactions. The strategy is based on the application of simple, cost-effective experimental techniques. The results from these techniques have been compared with those from commercially available instruments, and indicate a similar level of sensitivity. Results are presented for representative experimental systems, which demonstrate the application of the developed test methods as part of an overall thermal hazards assessment.